Product ID:SULFURIC ACID
MSDS Date:01/01/1988
FSC:6810
NIIN:00-146-7520
MSDS Number: BKHFP

E-C APPARATUS CORPORATION

3831 TYRONE BOULEVARD N.
ST. PETERSBURG, FL 33709

Emergency Phone: 813-344-1644

Info Phone: 813-344-1644

Preparer: WILLIAM W. GORMAN, JR.

Cage: 7Y829

E-C APPARATUS CORP.

SAINT PETERSBURG, FL 33709 US

Telephone: 800-356-0783

Cage: 7Y829

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 98%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER, H2O

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 2%

LD50 LC50 Mixture:ORAL LD50 (RAT): 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE DAMAGE, BLINDNESS, BURNS,
IRRITATION. SKIN: PAIN, BURNS, VESICULATION, SEVERE IRRITATION.
INHALATION: NOSE AND THROAT IRRITATION, HEADACHE, COUGH,
RESPIRATORY RATE INCREASE, CHEST TIGHTNE SS, CYANOSIS, PULMONARY
EDEMA. INGESTION: SEVERE BURNING IN MOUTH, THROAT, AND ABDOMEN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: LACRIMATION , CONJUNCTIVITIS. SKIN:
DERMATITIS. INHALATION: HYPOTENSION, CHRONIC TRACHEO-BRONCHITIS,
EMPHYSEMA, BRONCHIAL PNEUMONIA, TEETH DISCOLORATION AND EROSION.
INGESTION: DIARRHEA OF DARK, PRECIPITATED BLOOD, ASPHYXIA, THROAT
SWELLING, VOMITING, GASTROINTESTINAL PROBLEMS, ESOPHAGUS AND
STOMACH PERFORATION.
Medical Cond Aggravated by Exposure:RESPIRATORY AILMENTS

First Aid:EYES: FLUSH WITH PLENTY OF WATER. IN CASE OF BURNS, APPLY
STERILE BANDAGES LOOSELY WITHOUT MEDICATION. SKIN: WASH WITH SOAP
AND WATER. IN CASE OF CHEMICAL BURNS, COVER WITH STERILE, DRY
DRESSING. BAND AGE SECURELY. INHALATION: REMOVE TO FRESH AIR.
INGESTION: IF VICTIM IS CONSCIOUS, GIVE PLENTY OF WATER TO DILUTE
ACID. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IN ALL CASES.

Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE
Fire Fighting Procedures:WEAR SCBA WITH FULL FACE-PIECE IN POSITIVE
PRESSURE MODE. DO NOT USE WATER DIRECTLY ON MATERIAL. USE WATER
SPRAY/FOG TO ABSORB CORROSIVE VAPORS. KEEP UPWIND.
Unusual Fire/Explosion Hazard:MOVE CONTAINERS FROM FIRE AND COOL WITH
WATER. NEGLIGIBLE FIRE/EXPLOSION HAZARD WHEN EXPOSED TO HEAT OR
FLAME. RUNOFF TO SEWER MAY CREATE FIRE/EXPOSION HAZARD.

Spill Release Procedures:DIKE AREA FOR CONTAINMENT & ABSORB W/CEMENT
POWDER/FLY ASH. NEUTRALIZE W/SLAKED LIME/SODIUM BICARBONATE/CRUSHED
LIMESTONE TO PH7. DON'T PUT WATER ON/TOUCH SPILLED MATERIAL.
ISOLATE/ VENTILATE HAZARD A REA. KNOCK DOWN VAPORS W/WATER SPRAY;
KEEP UPWIND.
Neutralizing Agent:AGRICULTURAL/SLAKED LIME, CRUSHED LIMESTONE OR
SODIUM BICARBONATE.

Handling and Storage Precautions:FLAMMABLE/POISONOUS GASES MAY
ACCUMULATE IN CONFINED SPACES. AVOID BREATHING CORROSIVE VAPORS. 80
MG/M3 IS DANGEROUS TO LIFE AND HEALTH.
Other Precautions:DO NOT PUT WATER DIRECTLY ON MATERIAL. AVOID CONTACT
WITH MATERIAL. MAY IGNITE FINELY DIVIDED COMBUSTIBLE MATERIALS ON
CONTACT. WILL PRODUCE A VIOLENT EXOTHERMIC REACTION WITH WATER AND
ORGANIC MATERI ALS.

Respiratory Protection:WEAR GAS MASK W/CHIN-STYLE, FRONT/BACK-MOUNTED
ACID GAS CANISTER & HIGH-EFFICIENCY PARTICULATE FILTER/TYPE C
SUPPLIED-AIR RESPIRATOR/SCBA W/FULL FACE-PIECE/HELMET OR HOOD IN
OPERATED PRESSURE- DEMAND/ POSITIVE PRESSURE/CONTINOUS-FLOW MODE.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO KEEP < TLV.
Protective Gloves:PROTECTIVE
Eye Protection:SPLASH/DUST RESISTANT SAFETY GOGGLES
Other Protective Equipment:FACE SHIELD AND EYE-WASH FOUNTAIN
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING AND SHOES
IMMEDIATELY.
Supplemental Safety and Health
MAY IGNITE OTHER COMBUSTIBLE MATERIALS SUCH AS WOOD, PAPER, OIL, ETC.

HCC:C1
Boiling Pt:B.P. Text:536F,280C
Melt/Freeze Pt:M.P/F.P Text:37.0F,2.8C
Vapor Density:3.4
Spec Gravity:1.8
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS TO DARK BROWN, OILY LIQUID.

Stability Indicator/Materials to Avoid:YES
WATER, ORGANIC MATERIALS, ACIDS, ALCOHOLS, BASES, METALS, BROMATES,
CHLORINE, NITRIC ACID, SODIUM, POTASSIUM, ACETONE.
Stability Condition to Avoid:HIGH HEAT
Hazardous Decomposition Products:TOXIC FUMES OF SULFUR OXIDES,
POISONOUS GASES, HYDROGEN SULFIDE, HYDROGEN GAS

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE,
AND FEDERAL REGULATIONS.

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